A New Preconcentration Method of Hydrophobic Substances in Water Using Polyvinylmethylether as a Thermo-responsive Polymer. Application to Spectrophotometric Determination of a Trace Amount of Phosphate in Natural Water
- 1 May 1993
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 22 (5) , 849-850
- https://doi.org/10.1246/cl.1993.849
Abstract
A new method of concentration and separation for determining trace amounts of phosphate in natural water, using polyvinylmethylether(PVME), one of the thermally reverse polymers, was provided. When the solution was warmed to 45 °C, PVME shrank greatly, so that the phosphomolybdate Malachit Green aggregate stuck to the walls along with PVME.This publication has 5 references indexed in Scilit:
- Thermodynamic predictions of volume changes in temperature-sensitive gels. 2. ExperimentsMacromolecules, 1990
- Thermodynamic predictions of volume changes in temperature-sensitive gels. 1. TheoryMacromolecules, 1990
- Volume phase transition in a nonionic gelThe Journal of Chemical Physics, 1984
- Photometrische Bestimmung kleiner Phosphatmengen mit MalachitgrünAnalytical and Bioanalytical Chemistry, 1971
- Solution Properties of Poly(N-isopropylacrylamide)Journal of Macromolecular Science: Part A - Chemistry, 1968