Diphenylantimony(III) thiocyanate: unusual thiocyanate bridging
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 54-55
- https://doi.org/10.1039/c39910000054
Abstract
The thiocyanate group can bond via sulphur or nitrogen or bridge between two centres, but in diphenylantimony thiocyanate, unusual bridging gives antimony atoms coordinated by, respectively, two sulphur atoms, two nitrogen atoms and one atom of each type, allowing development of a curious infinite ‘triangular spiral’ structure in the solid state.Keywords
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