Static dielectric properties of polar solutions with nonpolar solvent
- 15 December 1973
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 59 (12) , 6478-6494
- https://doi.org/10.1063/1.1680028
Abstract
The dielectric behavior of a polar substance dissolved in a nonpolar liquid is studied by treating the system of induced dipoles as a dielectric continuum, in which the permanent dipoles of the solute are embedded. The interaction between permanent dipoles (consisting of an electrostatic plus a short range potential energy) is explicitly introduced into a linearized Boltzmann equation to study the correlation between dipoles at a given temperature. The theory is applied to a solution of chlorobenzene in benzene and of acetone in carbon tetrachloride: In both cases the experimental data are in good agreement with the behavior predicted by the theory.Keywords
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