Desulfurizative Germylation: Synthesis and Reaction of Allyl- and Allenylgermanes

Abstract
Allyl- and allenylgermanes were obtained by the reaction of allyl- or propargyl sulfur compounds with triphenylgermane in the presence of a radical initiator. Allylgermanes are as effective in the allylation of aldehydes as allylsilanes or stannanes.

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