Cooperative halide, perrhenate anion–sodium cation binding and pertechnetate extraction and transport by a novel tripodal tris(amido benzo-15-crown-5) ligand
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 13,p. 1253-1254
- https://doi.org/10.1039/a903440d
Abstract
A new tripodal tris(amido benzo-15-crown-5) ligand L1 cooperatively binds chloride, iodide and perrhenate anions via co-bound crown ether complexed sodium cations and efficiently extracts and transports the pertechnetate anion from simulated aqueous nuclear waste solutions via cooperative ion-pair binding effects.Keywords
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