The nature of the coordination bond in metal complexes of substituted pyridine derivatives. V. 4-Methylpyridine complexes of Zn(II), Cd(II), and Hg(II)
Open Access
- 15 December 1970
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 48 (24) , 3786-3789
- https://doi.org/10.1139/v70-639
Abstract
In this paper, an attempt is made to interpret the π-bonding between a 4-methylpyridine ligand and the divalent ions of zinc, cadmium, and mercury, using the previously introduced Rπ parameter. To do this, the ν12 mode in the complexes is assigned and confirmed by a normal coordinate analysis based on a valence force field model.Keywords
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