Synthesis, characterization, and properties of the pentamethylcyclopentadienyltetra-carbonylmetallates(0) of titanium and zirconium. Anionic and carbocyclic derivatives of zerovalent group 4 carbonyls, (C5Me5)M(CO)4 ?
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 331-332
- https://doi.org/10.1039/c39860000331
Abstract
Reductive carbonylations at atmospheric pressure of (C5Me5)MCl3(M = Ti and Zr), conducted at low temperature, provide thermally robust and crystalline products of the general formula [Et4N][(C5Me5)M(CO)4], which contain the first examples of carbonyl anions of titanium and zirconium.Keywords
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