Ein thermisch stabiler Peroxo‐Kupfer(II)‐Komplex mit ungewöhnlicher μ4‐Koordination des Peroxoliganden
- 5 October 1994
- journal article
- Published by Wiley in Angewandte Chemie
- Vol. 106 (19) , 2040-2041
- https://doi.org/10.1002/ange.19941061917
Abstract
Ein bei Raumtemperatur stabiler Peroxo‐Kupfer(II)‐Komplex ist das Kation von 1 (HL = 4‐Methyl‐2,6‐bis(pyrrolidinomethyl)phenol. Dieser Vierkernkomplex (Bild der zentralen Einheit rechts) weist mehrere ungewöhnliche Strukturdetails auf, unter anderem einen µ4‐ verbrückenden Peroxoliganden. Peroxo‐Kupfer(II)‐Komplexe sind im allgemeinen in‐stabile Verbindungen, die häufig nur spektroskopisch bei tiefen Temperaturen zu charakterisieren sind. • = Cu, ○ = O, ○ = N. magnified imageKeywords
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