Stabilisation of mononuclear palladium(III). The single crystal X-ray structure of the [Pd(L)2]3+cation (L = 1,4,7-trithiacyclononane)
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 987-988
- https://doi.org/10.1039/c39870000987
Abstract
Oxidation of the green [Pd(1)2]2+ cation [(1)= 1,4,7-trithiacyclononane] in 70% aqueous HClO4 affords the red [Pd(1)2]3+ cation, the single crystal X-ray structure of which shows a tetragonally distorted geometry about the PdIII centre with Pd–S(1) 2.5448(15), Pd–S(4) 2.3558(14), and Pd–S(7) 2.3692(15)Å.Keywords
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