The Temperature Dependence of the Trapped and Averaged-valence State in Mono-oxidized Dialkylbiferrocenes
- 1 May 1981
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 54 (5) , 1375-1379
- https://doi.org/10.1246/bcsj.54.1375
Abstract
An interesting temperature dependence of the valence state was observed in the Mössbauer spectra of the mixed-valence salts of 1′,1'″-dialkylbiferrocenes, measured at various temperatures from 4.2 K to 300 K. A mechanistic consideration of the temperature dependence has been carried out assuming a conformational change of the monocation salts induced both by the variation in the temperature and by the kind of counter anion.This publication has 13 references indexed in Scilit:
- Nitrogen Determination by Pyrolysis Using Steam. I.Bulletin of the Chemical Society of Japan, 1980
- Preparation, physical properties, and x-ray structure of the mixed-valence compounds diferrocenylselenium iodine triiodide hemi(methylene chloride)Journal of the American Chemical Society, 1980
- Electron transfer in oxidized biferrocene, biferrocenylene, and [1.1]ferrocenophane systemsInorganic Chemistry, 1975
- Mixed-valence ferrocene systems temperature dependence in the mössbauer spectra of [Fe(II)Fe(III) [1.1] ferrocenophanesChemical Physics Letters, 1973
- Intervalence transfer in biferricenium and biferricenylenium cationsThe Journal of Chemical Physics, 1973
- Mössbauer spectra and thermal electron transfer in mixed valence iron compoundsJournal of Inorganic and Nuclear Chemistry, 1972
- Organic solid state. IV. Effect of environment on electron transfer in biferrocene[iron(II)iron(III)] picrateThe Journal of Physical Chemistry, 1971
- Mössbauer Study of Electron Hopping in the Octahedral Sites of Fe3O4Journal of Applied Physics, 1969
- Observation of electron hopping in 151Eu3S4 by Mössbauer spectroscopySolid State Communications, 1968
- Mössbauer Studies of Iron Organometallic Complexes. IV. Sign of the Electric-Field Gradient in FerroceneThe Journal of Chemical Physics, 1965