Nucleophilic Additions of Phosphorus Compounds to Aromatic Methyleneamines
- 1 January 1990
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1990 (05) , 261-262
- https://doi.org/10.1055/s-1990-21056
Abstract
Aromatic methyleneamines 2 or their precursors N-(alkoxymethyl)arylamines 1 react with lithium phosphides or secondary phosphines to give N-(phosphinomethyl)arylamines 3. In the same way, dialkyl or diaryl phosphites are added to 1 producing (arylaminomethyl)phosphonates 5. This new one-pot method allows the synthesis of phosphorus derivatives 3 and 5 in high yield.Keywords
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