Synthesis of New Optically Active Bis- and Tris(phosphines)

Abstract
The synthesis of new optically active alkanediylbis- and alkanetriyltris(diphenylphosphines) is described. Easily accessible optically pure lactones and carboxylic acids are reduced to the alcohols, tosylated and reacted with lithium diphenylphosphide to give the corresponding phosphines.

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