Metallorganische verbindungen des iridiums und rhodiums: XXVI. CH-metallierung und hydridbildung im system Ir2Cl2(C8H14)4/PR3(PR3 = P(CH2CMe3)3, t-BuP(CH2CMe3)2, t-Bu2PCH2CMe3; i-Pr3P
- 27 August 1985
- journal article
- Published by Elsevier in Journal of Organometallic Chemistry
- Vol. 291 (3) , 371-386
- https://doi.org/10.1016/0022-328x(85)80189-3
Abstract
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This publication has 24 references indexed in Scilit:
- Alkyl- und arylkomplexe des iridiums und rhodiums: XV. Phosphonit- und phosphinitinduzierte co-insertions- und C-H-additionsreaktionen ortho-methylsubstituierter iridiumaryle. Reversible CH3-metallierung im phosphinitkomplexH2-2](Ph2POMe)3Journal of Organometallic Chemistry, 1983
- Alkyl- und arylkomplexe des iridiums und rhodiums XII. Phosphitinduzierte co-insertions- und C H-additionsreaktionen ortho-alkylsubstituierter iridiumaryle: synthese und struktur zweier metallazyklischer verbindungen HR-2][P(OMe)3]3 (R CH3, H)Journal of Organometallic Chemistry, 1983
- Cyclometallation reactions inortho-methyl substituted iridium arylsvia CO insertion and oxidative C-H addition. Characterization of the reported IrH[C6H2Me2-(4,6)-CH2-(2)][P(OMe)3]3 as the internally metallated benzoyl complexfac-IrH[C(O)C6H2Me2-(4,6)-H2(2)]-[P(OMe)3]3 by X-Ray diffraction(1)Transition Metal Chemistry, 1980
- Cyclometalation at carbon adjacent to oxygen in platinum(II) and iridium(I) phosphine complexesJournal of Organometallic Chemistry, 1979
- Activation of CH bonds by transition metalsJournal of Organometallic Chemistry, 1979
- Ligandeninduzierte intramolekulare oxidative Additionen von Methyl‐C - H‐Bindungen: ortho ‐methylsubstituierte Arylkomplexe des Iridiums(I) und deren Reaktionen mit Phosphinen und PhosphitenEuropean Journal of Inorganic Chemistry, 1978
- Activation of CH bonds by transition metals: IV. Partial dehydrogenation of tricyclohexylphosphine by iridium(I) and rhodium(I) leading to the formation of a metal—olefin complex and a five-coordinated metal dihydride, which is a hydrogenation catalystJournal of Organometallic Chemistry, 1978
- Activation of CH bonds by transition metals : III. Metallation of alkylphosphines coordinated to iridium(I)Journal of Organometallic Chemistry, 1977
- Activation of CH bonds by transition metals: II. Metallation of allylphosphines by (acac)Ir(C2H4)2Journal of Organometallic Chemistry, 1977
- Activation of CH bonds by transition metals I. Metallation of allylphosphines coordinated to iridium(I)Journal of Organometallic Chemistry, 1976