Simple generation of a reactive glycosyl-lithium derivative
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 355-356
- https://doi.org/10.1039/c39840000355
Abstract
Two-step hydrolithiation of 3,4,6-tri-O-benzyl-D-glucal (hydrochlorination and lithium naphthalenide reductive lithiation) gives a reactive glycosyl-lithium derivative which is shown to be a precursor of C-glycosides.Keywords
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