Anomalous equilibration of (Z)-N-[1-(1-naphthyl)ethylidene]isopropylamine in [2H4]methanol: a kinetic chimera involving an apparent equilibrium overshoot
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 443-444
- https://doi.org/10.1039/c39850000443
Abstract
Unexpected equilibrium overshoot observed during the isomerization of the title imine in [2H4]methanol is rationalised in terms of a biased kinetic deuterium isotope effect, and isomerization via an enamine intermediate.Keywords
This publication has 0 references indexed in Scilit: