Bistrimethylsilylthioketen: a versatile reagent for thioketen-based syntheses
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1008-1009
- https://doi.org/10.1039/c39760001008
Abstract
The stable thioketen, (Me3Si)2CCS (1), reacts with alcohols and amines to give O-alkyl thio-esters Me3SiCH2C(S)OR (2), and thioamides, Me3SiCH2C(S)NR2(3), which can be desilylated or metallated for further use in synthesis; the isomeric Me3SiCCSSiMe3(8) thermally rearranges to (1).Keywords
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