A short, efficient route to a protected daunosamine from L-rhamnose
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 1031-1032
- https://doi.org/10.1039/c39830001031
Abstract
The imidate ester obtained from the reaction of methyl 2,3,6-trideoxy-α-L-threo-hex-2-enopyranoside with trichloroacetonitrile undergoes iodonium ion-induced cyclisation, and the dihydroxazole product is subjected to reductive dehalogenation to give a protected from of daunosamine.Keywords
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