Electrified microheterogeneous catalysis in low ionic strength media
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 25-27
- https://doi.org/10.1039/c39930000025
Abstract
The ability to drive catalytic processes when dc voltages are applied to low ionic strength dispersions has been demonstrated for the selective partial oxidation of propene at 0 °C in an aqueous dispersion of PdII–CuII supported on Y zeolite where the primary partial oxidation product can be either acetone or propylene oxide depending on the nature of the dispersed solid; in the absence of the applied electrifying force no product forms and in the absence of the molecular catalyst no selective oxidation occurs.Keywords
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