Hydroxy-assisted chemo- and stereo-selective epoxidation catalysed by a titanium silicate molecular sieve (TS-1)/H2O2 system
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 1315-1316
- https://doi.org/10.1039/c39950001315
Abstract
The TS-1/H2O2 system efficiently catalyses the hydroxy-assisted chemoselective epoxidation of α-hydroxyalkene in geraniol, and the stereoselective epoxidation of cyclopent-2-en-1-ol/cyclohex-2-en-1-ol producing the epoxide which is cis to OH with high selectivity (90:10 cis: trans).Keywords
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