PHOTOCHEMICAL TRANSFORMATIONS OF DIENES: I. THE PHOTOLYSIS OF 3-ALKOXYCHOLESTA-3,5-DIENES
- 1 January 1964
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 42 (1) , 79-83
- https://doi.org/10.1139/v64-013
Abstract
The photolysis of 3-alkoxycholesta-3,5-dienes in an alcohol has been found to result in a stereospecific addition of the alcohol to the Δ3 double bond with formation of β,γ-unsaturated ketals. On silica gel, the non-cyclic β,γ-unsaturated ketals gave cholest-5-en-3-one.Keywords
This publication has 2 references indexed in Scilit:
- PHOTOCHEMICAL TRANSFORMATIONS. V. THE REACTION OF 3,5-CHOLESTADIENE1,2Journal of the American Chemical Society, 1959
- Neighboring Carbon and Hydrogen. XVI. 1,3-Interactions and Homoallylic ResonanceJournal of the American Chemical Society, 1954