Nanostructured SiC/BN/C ceramics derived from mixtures of B3N3H6 and [HSi(Me)C≡C]n
- 1 June 2006
- journal article
- Published by Walter de Gruyter GmbH in International Journal of Materials Research
- Vol. 97 (6) , 721-728
- https://doi.org/10.3139/146.101294
Abstract
Three borazine-modified polycarbosilanes were synthesized by reaction of poly[1,2-ethynediyl-(methylsilylene)], [HSi(Me)C≡C]n, and borazine, B3N3H6 using different stoichiometries. The polymeric precursors were transformed into inorganic Si–B–C–N materials by solid state thermolysis at 1400°C each in 88% yield. High temperature thermogravimetric analysis in an argon atmosphere showed no substantial decomposition reactions below 1800°C. Crystallization behavior up to 2000°C in a nitrogen atmosphere was studied by post-thermolysis heat treatment of as-obtained ceramics at various temperatures and subsequent examination of samples at room temperature using powder X-ray diffraction. Ceramics annealed at 1800°C were additionally characterized by transmission electron microscopy.Keywords
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