Thermal decomposition and cobalt-carbon bond dissociation energies of organocobalamins: neopentyl-, (cyclopentylmethyl)-, (cyclohexylmethyl)-, (tetrahydrofurfuryl)- and ((tetrahydro-2H-pyryl)methyl)cobalamin
- 1 May 1988
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 110 (10) , 3120-3126
- https://doi.org/10.1021/ja00218a021
Abstract
No abstract availableKeywords
This publication has 7 references indexed in Scilit:
- Thermolysis of the cobalt-carbon bond of adenosylcobalamin. 2. Products, kinetics, and cobalt-carbon bond dissociation energy in aqueous solutionJournal of the American Chemical Society, 1986
- Complete proton and carbon-13 assignments of coenzyme B12 through the use of new two-dimensional NMR experimentsJournal of the American Chemical Society, 1986
- Homolysis and electron-transfer reactions of benzylcobalaminJournal of the American Chemical Society, 1985
- The chemistry of vitamin B12. Part 25. Mechanism of the β-elimination of olefins from alkylcorrinoids; evidence for an initial homolytic fission of the Co–C bondJ. Chem. Soc., Dalton Trans., 1985
- Sterically induced, spontaneous cobalt-carbon bond homolysis and .beta.-elimination reactions of primary and secondary organocobalaminsJournal of the American Chemical Society, 1981
- Reactions of vitamin B12r with organic halidesJournal of the American Chemical Society, 1980
- Chemistry of cobalamins and related compounds. 48. Sterically induced, spontaneous dealkylation of secondary alkylcobalamins due to axial base coordination and conformational changes of the corrin ligandJournal of the American Chemical Society, 1979