A novel hexanuclear heteropolyperoxo oxidation catalyst: preparation, X-ray crystal structure and reactions of [NMe4]3[(MePO3){MePO2(OH)}W6O13(O2)4(OH)2(OH2)]·4H2O
- 1 January 1995
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 2183-2184
- https://doi.org/10.1039/c39950002183
Abstract
The crystal structure of the title compound, 1, reveals the presence of two distinct types of tungsten atom in which the four bearing peroxo groups have distorted pentagonal-bipyramidal geometries and the remaining two are octahedral; 1 is an effective catalyst for monoalkene epoxidation, and the oxidation of primary and secondary alcohols, with H2O2 as co-oxidant.Keywords
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