An X-Ray Diffraction Study of Precipitated Cadmium Sulphide
- 1 October 1964
- journal article
- Published by IOP Publishing in Japanese Journal of Applied Physics
- Vol. 3 (10)
- https://doi.org/10.1143/jjap.3.626
Abstract
Powders of cadmium sulphide were precipitated with hydrogen sulphide from aqueous solutions of cadmium chloride, bromide, nitrate, and sulphate (and from various mixtures of them) under widely varied concentrations, pH values, and temperatures, and inspected by X-ray diffraction. Hexagonal α-CdS tends to be precipitated from halide solutions, and cubic β-CdS from nitrate and sulphate solutions. Precipitates seem, however, invariably to involve stacking faults of the type proposed in a previous report (R. Sato: Acta Cryst. 15 (1962) 1109). Effects of precipitation conditions on `hexagonality' (fraction of the hexagonal stacking sequence in the crystal) and crystallite-size of products are presented. Attentions are paid to colours of precipitates.Keywords
This publication has 10 references indexed in Scilit:
- Stacking fault in precipitated cadmium sulphideActa Crystallographica, 1962
- Structure of Precipated Cadmium Sulphide as studied by Single-Crystal Electron Diffraction PatternNature, 1959
- The effect of pressure on zinc blende and wurtzite structuresJournal of Physics and Chemistry of Solids, 1959
- Ein Beitrag zur Kinetik der FällungskristallisationColloid and Polymer Science, 1959
- Eindimensionale Fehlordnung in Kristallen und ihr Einfluss auf die Röntgeninterferenzen. III. Vergleich der Berechnungen mit experimentellen ErgebnissenActa Crystallographica, 1949
- Eindimensionale Fehlordnung in Kristallen und ihr Einfluss auf die Röntgeninterferenzen. I. Berechnung des Fehlordnungsgrades aus den RöntgenintensitätenActa Crystallographica, 1949
- Eindimensionale Fehlordnung in Kristallen und ihr Einfluss auf die Röntgeninterferenzen. II. Berechnung der fehlgeordneten dichtesten Kugelpackungen mit Wechselwirkungen der Reichweite 3Acta Crystallographica, 1949
- Studies on the Coprecipitation of Cadmium and Mercuric Sulfides.The Journal of Physical Chemistry, 1943
- La diffraction des rayons X dans quelques solutionsPhysica, 1935
- The Color and Crystal Structure of Precipitated Cadmium Sulfide.The Journal of Physical Chemistry, 1934