Crystal structures of quinolinyl palladium(II) complexes: [Pd(PPh3)2{κ1-C9H6NB}(Cl)] and [Pd(PPh3)2Cl]2{μ,κ2-C9H6N}
- 1 January 2020
- journal article
- research article
- Published by NIIC SB RAS in Журнал структурной химии
- Vol. 61 (9) , 1508-1514
- https://doi.org/10.26902/jsc_id60689
Abstract
A reaction of Pd(PPh3)4 (complex 1) and 2-chloroquinoline C9H6NCl in a 1:1 molar ratio produces a mononuclear [Pd(PPh3)2{κ1-C9H6NB}(Cl)] complex (complex 2) and a binuclear [Pd(PPh3)2Cl]2{μ,κ2-C9H6N} complex (complex 3). In complex 3, each of quinoline units is bridged through the carbon atom of quinoline groups to one metal center and the nitrogen atom to another metal, forming a six-membered ring with the boat-like geometry. Complexes 2 and 3 are characterized by the elemental analysis, fast atom bombardment mass spectrometry, 31P NMR spectroscopy, and single crystal X-ray diffraction.Keywords
This publication has 0 references indexed in Scilit: