Regiospecific Carboalkoxylation of 2,5-Dibromopyridine
- 1 February 1997
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 27 (3) , 515-520
- https://doi.org/10.1080/00397919708006053
Abstract
Carboalkoxylation of 2,5-dibromopyridine with carbon monoxide and an alcohol in the presence of palladium acetate and 1,1′-bis(diphenylphosphino) ferrocene (dppf) occurs regiospecifically to afford esters of 5-bromo-pyridine-2-carboxylic acid in good yield.Keywords
This publication has 8 references indexed in Scilit:
- Synthesis and Biological Activities of New HMG-CoA Synthase Inhibitors: 2-Oxetanones with a Side Chain Containing Biphenyl, Terphenyl or PhenylpyridineHETEROCYCLES, 1994
- A convenient palladium-catalyzed coupling approach to 2,5-disubstituted pyridinesThe Journal of Organic Chemistry, 1988
- Palladium-catalyzed carbonylation of aryl triplates. Synthesis of arenecarboxylic acid derivatives from phenolsTetrahedron Letters, 1986
- Synthesis and Deuteration of Some Halogenoquinoli-zinium BromidesHETEROCYCLES, 1981
- Selective halogen-lithium exchange in 2,5-dibromobenzenes and 2,5-dibromopyridineThe Journal of Organic Chemistry, 1977
- Palladium-catalyzed carboalkoxylation of aryl, benzyl, and vinylic halidesThe Journal of Organic Chemistry, 1974
- The synthesis of some substituted methyl pyridinecarboxylates. II. Methyl 4-substituted picolinates, methyl 5-substituted picolinates, and methyl 5-substituted nicotinatesAustralian Journal of Chemistry, 1971
- Über das 2‐Methyl‐5‐amino‐pyridin und seine DerivateJournal für Praktische Chemie, 1932