Synthesen mit aliphatischen Dialdehyden, XXXV. Synthesen mit 1- und 2-Adamantylmalonaldehyd/ Syntheses with Aliphatic Dialdehydes, XXXV. Syntheses with 1- and 2-Adamantyl Malonaldehyde
Open Access
- 1 September 1982
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 37 (9) , 1187-1195
- https://doi.org/10.1515/znb-1982-0918
Abstract
The reaction of 1- (1) and 2-adamantyl malonaldehyde (2) with suitable electrophiles and nucleophiles yields adainantyl-substituted open-chain (3-5), carbocyclic (6) as well as heterocyclic compounds (7-19) with peculiar properties due to the presence of the lipophilic adamantyl group. The tetrazolo[1,5-a]pyrimidine (16) exhibits a solvent-dependent tetrazolo-azido valence isomerization reaction.Keywords
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