Chemistry of acetylenic ethers 73: Alkali amide cleavage of allenyl thioethers
- 1 January 1964
- journal article
- research article
- Published by Wiley in Recueil des Travaux Chimiques des Pays-Bas
- Vol. 83 (5) , 456-460
- https://doi.org/10.1002/recl.19640830503
Abstract
Allenyl thioethers of the type CH3CHC (R = alkyl) have been converted in very good yield into 1,3‐enynes HCC‐CHCH‐R (IV) on treatment with two equivalents of alkali amide in liquid ammonia, followed by hydrolysis of the reaction mixture.Keywords
This publication has 3 references indexed in Scilit:
- Chemistry of acetylenic ethers 68: Preparation of enynes by elimination of alcohol from acetylenic ethersRecueil des Travaux Chimiques des Pays-Bas, 1963
- Chemistry of acetylenic ethers, 67: Allenyl thioethers from alkynyl thioethersRecueil des Travaux Chimiques des Pays-Bas, 1963
- Chemistry of acetylenic ethers. LXI: A simple method for the preparation of acetylenic thioethers, selenoethers and telluroethers (Preliminary publication)Recueil des Travaux Chimiques des Pays-Bas, 1962