Excluded volume and hyperscaling in polymeric systems
- 1 January 1985
- journal article
- Published by EDP Sciences in Journal de Physique Lettres
- Vol. 46 (17) , 837-843
- https://doi.org/10.1051/jphyslet:019850046017083700
Abstract
A dense system of mutually avoiding polymers, obeying a quenched power-law mass distribution, n(m) ∼ m-τ (with low and high cutoffs) is considered in d dimensions. It is argued that, for a certain range of τ (d/dfg < τ - 1 < d/dfs), the chains are neither Gaussian (fractal dimension df = dfg) nor fully swollen (d f = dfs), but instead obey exactly a hyperscaling relation, df = d/(τ - 1). This result applies both to linear polymers (dfg = 2, d fs = 1/ν(d)) and to « polymeric fractals » (e.g., sol-molecules) of general connectivity. Scaling laws for dilution are also givenKeywords
This publication has 10 references indexed in Scilit:
- Kinetics of Formation and Mean Shape of Branched PolymersPhysical Review Letters, 1985
- Statics and Dynamics of Polymeric FractalsPhysical Review Letters, 1984
- Elastic Properties of Random Percolating SystemsPhysical Review Letters, 1984
- Branched polymer approach to the structure of lattice animals and percolation clustersJournal of Physics A: General Physics, 1984
- Density of states on fractals : « fractons »Journal de Physique Lettres, 1982
- Equilibrium Polymerization as an Ising ModelPhysical Review Letters, 1981
- Kinetics of polymerizationJournal of Statistical Physics, 1980
- Flory exponents for generalized polymer problemsJournal de Physique Lettres, 1980
- The theory of polymer solutions at intermediate concentrationProceedings of the Physical Society, 1966
- The Configuration of Real Polymer ChainsThe Journal of Chemical Physics, 1949