Syntheses, Structures, and Solid State Properties of One-Dimensional Halogen-Bridged Ni111−X-Ni111Compounds (X˭Cl and Br)
- 1 April 1990
- journal article
- research article
- Published by Taylor & Francis in Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics
- Vol. 181 (1) , 333-342
- https://doi.org/10.1080/00268949008036017
Abstract
Halogen-bridged linear-chain compounds, {[Ni(R,R-chxn)2X]X2}∞ (X˭C1 and Br), were synthesized and their structures have been determined by low-temperature X-ray diffraction analyses. The novel one-dimensional Ni111 -X-Ni111 structure with no Peierls distortion, which is an extreme limit of the MII -X-MIV mixed-valKeywords
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