Dipole moment matrix for vibration - rotation transitions in C3v molecules
- 1 January 1984
- journal article
- Published by EDP Sciences in Journal de Physique
- Vol. 45 (9) , 1429-1447
- https://doi.org/10.1051/jphys:019840045090142900
Abstract
The transformed dipole moment or C3v molecules has been worked out up to second order of approximation on the basis of its invariance properties. Its dependence on the total angular momentum components has been made explicit. The dipole moment matrix has been written with a view to calculate vibration-rotation intensities in the case of strongly interacting vibrational polyads. The importance of a coherent phase system for correct intensity calculations has been emphasizedKeywords
This publication has 1 reference indexed in Scilit:
- The Asymmetric Rotor II. Calculation of Dipole Intensities and Line ClassificationThe Journal of Chemical Physics, 1944