Ferro- and ferri-magnetism in oximato-bridged MIIICuIIchains (M = Mn and Fe). A molecular based ferromagnet with Tc= 9 K: [MnIIICuII-bis(1,2-cyclohexanedioneoximato)(acetato)(H2O)2]
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 2615-2616
- https://doi.org/10.1039/c39940002615
Abstract
The study of the magnetic properties of the compounds [MIIICuII(L)2(MeCO2)(H2O)2], M = Mn and L = dimethylglyoximato (dmg)1 or 1,2-cyclohexanedioneoximato (chd)2 and M = Fe and L = dmg 3, shows that 1 is a metamagnetic compound, 2 is a bulk ferromagnet with Tc= 9 K and 3 orders antiferromagnetically at 7.5 K.Keywords
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