One-Pot Synthesis of Secondary and Tertiary Amines by Carbonylative Hydroaminomethylation of Alkenes Catalyzed by Di(μ-chloro)bis(η4-1,5-cyclooctadiene)dirhodium
- 1 November 1997
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1997 (11) , 1331-1337
- https://doi.org/10.1055/s-1997-1338
Abstract
Secondary and tertiary amines are selectively prepared with high yields by the reaction of alkenes with primary or secondary amines, carbon monoxide and hydrogen in the presence of [Rh(cod)Cl]2 as catalyst via a one-pot hydroformylation - amine condensation - reduction sequence.Keywords
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