High‐pressure range of the recombination O + O2 → O3
- 1 December 1984
- journal article
- research article
- Published by Wiley in International Journal of Chemical Kinetics
- Vol. 16 (12) , 1519-1529
- https://doi.org/10.1002/kin.550161206
Abstract
The recombination reaction O + O2 → O3 was studied by laser flash photolysis of pure O2 in the pressure range 3–20 atm, and of N2OO2 mixtures in the bath gases Ar, N2, (CO2, and SF6) in the pressure range 3–200 atm. Fall‐off curves of the reaction have been derived. Low‐pressure rate coefficients were found to agree well with literature data. A high‐pressure rate coefficient of k∞ = (2.8 ± 1.0) × 10−12 cm3 molecule−1 s−1 was obtained by extrapolation.Keywords
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