Chiral Anionic Surfactants for Asymmetric Mukaiyama Aldol-Type Reaction in Water
- 1 March 2003
- journal article
- research article
- Published by SAGE Publications in Journal of Chemical Research
- Vol. 2003 (3) , 153-156
- https://doi.org/10.3184/030823403103173318
Abstract
Sulfonate derivatives of chiral 1,1′-binaphthol were used as chiral anionic surfactants in asymmetric aldol-type reaction in water to give aldol adducts with moderate to good diastereo- and enantioselectivities; Ga(OTf)3 and Cu(OTf)2 were better than Sc(OTf)3 as Lewis acid catalysts.Keywords
This publication has 11 references indexed in Scilit:
- A Novel Chiral Lead(II) Catalyst for Enantioselective Aldol Reactions in Aqueous MediaJournal of the American Chemical Society, 2000
- Calix[6]arene derivatives bearing sulfonate and alkyl groups as surfactants in Sc(OTf)3-catalyzed Mukaiyama aldol reactions in waterTetrahedron Letters, 2000
- Catalytic asymmetric Mukaiyama aldol reactions in aqueous mediaTetrahedron, 1999
- Lanthanide Triflate-Catalyzed Carbon-Carbon Bond-Forming Reactions in Organic SynthesisPublished by Springer Nature ,1999
- Lewis acid catalysis in micellar systems. Sc(OTf)3-Catalyzed aqueous aldol reactions of silyl enol ethers with aldehydes in the presence of a surfactantTetrahedron Letters, 1997
- The Chemistry of Trichlorosilyl Enolates. 2. Highly-Selective Asymmetric Aldol Additions of Ketone EnolatesJournal of the American Chemical Society, 1997
- The asymmetric induction and catalysis of chiral reverse micelle: Asymmetric reduction of prochiral ketonesTetrahedron: Asymmetry, 1996
- Organic reactions in chiral micelles: 7. The structural effects on the asymmetric oxidation of prochiral sulfides in chiral micellesChinese Journal of Chemistry, 1990
- C2 symmetry and asymmetric inductionChemical Reviews, 1989
- NEW ALDOL TYPE REACTIONChemistry Letters, 1973