Intramolecular C-alkylation in diazo-ketones
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 14,p. 773-774
- https://doi.org/10.1039/c29710000773
Abstract
A new annelation reaction, initiated by the protonated diazomethylcarbonyl function, has been utilized in the incorporation of the bicyclo[3,2,1]octane moiety into a variety of intermediates for the total synthesis of tetracyclic diterpenoids.Keywords
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