Calculation of the entropy of binary hard sphere mixtures from pair correlation functions
- 1 August 1992
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 97 (3) , 2153-2155
- https://doi.org/10.1063/1.463103
Abstract
We evaluate the entropy of several binary hard sphere fluid mixtures using two approximate expressions that require as input only the pair correlation functions, gαβ(r). An approximation based on the incompressible limit is found to be accurate for medium to high density fluids.Keywords
This publication has 14 references indexed in Scilit:
- Entropy of hydrophobic hydration: a new statistical mechanical formulationThe Journal of Physical Chemistry, 1992
- Calculation of the entropy from multiparticle correlation functionsPhysical Review A, 1992
- Thermodynamic properties of binary hard sphere mixturesMolecular Physics, 1991
- Computer simulation of solid-liquid coexistence in binary hard sphere mixturesMolecular Physics, 1991
- Dominant forces in protein foldingBiochemistry, 1990
- Thermodynamic potentials and distribution functionsMolecular Physics, 1990
- Direct entropy calculation from computer simulation of liquidsPhysical Review A, 1989
- Entropy and Molecular Correlation Functions in Open Systems. I. DerivationThe Journal of Chemical Physics, 1971
- Some Factors in the Interpretation of Protein DenaturationAdvances in Protein Chemistry, 1959
- Analysis of Classical Statistical Mechanics by Means of Collective CoordinatesPhysical Review B, 1958