Synthesis of an oxorhenium(V) corrolate from porphyrin with detrifluoromethylation and ring contraction
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 11,p. 1199-1200
- https://doi.org/10.1039/a802033g
Abstract
Metallation of highly electron deficient 5,10,15,20-tetrakis(trifluoromethyl)porphyrin 1 with [Re2(CO)10] in refluxing PhCN resulted in a novel synthesis of oxorhenium(V) 5,10,15-tris(trifluoromethyl)corrolate 2 characterized by single crystal X-ray crystallography.Keywords
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