Enantioselective Alternating Terpolymerization of Styrene and Ethene with Carbon Monoxide. Preliminary communication
- 12 January 1998
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 81 (1) , 35-39
- https://doi.org/10.1002/hlca.19980810104
Abstract
In spite of the higher reactivity of styrene with respect to ethene for the alternating copolymerization with carbon monoxide, catalyzed by chiral (dihydrooxazole)(phosphino)palladium complexes, ethene is preferentially (and randomly) enchained in terpolymerization experiments; enantioface selection for styrene is comparably high in both copolymerization and terpolymerization processes.Keywords
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