Preparation of derivatives of tricyclo[4.2.0.01,4]octane, broken window compounds
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 118-120
- https://doi.org/10.1039/c39810000118
Abstract
Photolysis of 3-(3-methylbut-3-enyl)cyclopent-2-enone (4) leads to the tricyclo [5.2.0.01,5]nonane (5); the derived diazoketone (7) undergoes Wolff rearrangement to give esters (8) and (9), derivatives of tricyclo [4.2.0.01,4]octane (1).Keywords
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