The polymerization mechanism and kinetics of DGEBA with BF3‐MEA

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Abstract
The diglycidyl ether of bisphenol‐A (DGEBA) and boron trifluoride monoethylamine (BF3‐MEA) were used in a model system to investigate the chemical and physical changes that occur during polymerization. Experiments using 19F and 1H nuclear magnetic resonance (NMR) and Fourier transform infrared spectroscopy (FTIR) showed that BF3‐MEA breaks down rapidly into HBF4 and an amine salt at 85°C and above. The HBF4 complexes with the epoxy groups, producing an activated monomer that reacts with epoxy in an etherification reaction. A mechanism is proposed whereby activated epoxy sites (complexes) continuously add epoxy throughout the reaction, but where unactivated epoxies (monomer molecules) are unable to react with each other. The reaction rate and mode (kinetic vs. diffusion control) therefore are strongly influenced by the BF3‐MEA concentration and the reaction temperature. © 1993 John Wiley & Sons, Inc.

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