Synthesis and X-ray crystal structure of a novel paramagnetic organotitanium(III) compound, cyclopentadienyl-bis[o-(NN-dimethylaminomethyl)phenyl]titanium
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 942-943
- https://doi.org/10.1039/c39760000942
Abstract
The reaction of Li-o-C6H4CH2NMe2(2 equiv.) with [(C5H5)TiCl2]x in ether gives the novel, air-sensitive, paramagnetic complex (C5H5)Ti(o-C6H4CH2NMe2)2(1), whose crystal structure has been determined; (1) reacts with CO2 and exchanges the cyclopentadienyl hydrogens with D2.Keywords
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