An Efficient Route to Unsymmetrical Biaryls via the Electrochemical Preparation of Functionalized Aromatic Zinc Organometallics
- 1 January 1993
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1993 (06) , 425-426
- https://doi.org/10.1055/s-1993-22481
Abstract
Various functionalized aromatic or heteroaromatic zinc organometallics, which were prepared electrochemically from aryl chlorides or -bromides in the presence of a nickel-complex catalyst and zinc ions, reacted with aromatic or heteroaromatic halides in the presence of catalytic amounts of palladium phosphine complexes to give unsymmetrical biaryls in good to excellent yields.Keywords
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