Potential-Energy Curves for CO and CO+
- 1 September 1965
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 43 (5) , 1529-1534
- https://doi.org/10.1063/1.1696966
Abstract
Potential‐energy curves for the X 1Σ+, A 1Π, I 1Σ−, a 3Π, a′ 3Σ+, d 3Δi, and e 3Σ− electronic states of CO and the X 2Σ+, A 2Πi, and B 2Σ+ electronic states of CO+ have been calculated using a modification of the Rydberg—Klein—Rees method. The curves for the a 3Π, d 3Δi, and A 2Πi states, which are intermediate between Hund's Cases (a) and (b), represent fictitious rotationless states calculated using the true Bv. Benesch and co‐workers have shown theoretically that this representation is correct for such intermediate cases. The numerical results for the A 2Πi state presented here confirm their conclusions.Keywords
This publication has 11 references indexed in Scilit:
- On the Recalculation of the Potential Curves for the Ground States of I2 and H2The Journal of Chemical Physics, 1963
- The State I1 -of Carbon MonoxideProceedings of the Physical Society, 1962
- Modification of the Rydberg—Klein—Rees Method for Obtaining Potential Curves for Doublet States Intermediate Between Hund's Cases (a) and (b)The Journal of Chemical Physics, 1962
- Structure of the Triplet Bands of COThe Journal of Chemical Physics, 1962
- Potential Energy Curves for COThe Journal of Chemical Physics, 1960
- Ground state of hydrogen by the Rydberg-Kelein-Rees methodJournal of Molecular Spectroscopy, 1959
- Absorption Spectrum of CO in the Vacuum Ultraviolet RegionThe Journal of Chemical Physics, 1957
- The Band Spectrum of CO^{+}. II. Comet-Tail System (A^{2}II-X^{2}Σ).The Astrophysical Journal, 1950
- Über die Struktur der Triplettbanden (d3II→a3II) des KohlenoxydsAnnalen der Physik, 1939
- The Red CN Band SystemPhysical Review B, 1932