Cyclic voltammetry studies on the complexation of metal cations by cryptands containing the ferrocene unit
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 419-421
- https://doi.org/10.1039/c39890000419
Abstract
The co-ordination of alkaline-earth and lanthanide metal cations by a cryptand containing the ferrocene unit has been examined by cyclic voltammetry; the data are used to deduce values of K2 for the association of oxidised cryptand (1+) with this range of metal cations and a linear correlation between ln K2 and the ratio of ionic radius/ionic charge is reported.Keywords
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