Preparation and Structure of a Mixed Benzenethiolatosulfido Trinuclear Nickel Complex
- 5 May 1988
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 17 (5) , 823-826
- https://doi.org/10.1246/cl.1988.823
Abstract
X-Ray structure analysis of [Ni3S(SPh)6]2− has revealed that a central μ3-S and three Ni atoms form a trigonal pyramid, a μ-SPh ligand bridges each pair of the three Ni atoms situated at the apexes of a triangle, and each Ni is terminally coordinated by SPh, completing a trinuclear complex. The stereochemistry around Ni is tetrahedrally distorted square planar.This publication has 9 references indexed in Scilit:
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