Ruthenium-catalysed C–H bond activation. Evidence for a concerted mechanism in oxyfunctionalization of cyclic saturated hydrocarbons
- 1 January 1990
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1344-1345
- https://doi.org/10.1039/c39900001344
Abstract
Oxidation of bridged polycyclic alkanes with in situ generated RuO4 occurs by a concerted mechanism involving interaction of the highly electrophilic oxoruthenium species with tertiary unhindered C–H bonds.Keywords
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