Novel High Rate Lithium Intercalation Cathode Materials
- 1 January 2002
- journal article
- Published by The Electrochemical Society in Journal of the Electrochemical Society
- Vol. 149 (2) , A99-A102
- https://doi.org/10.1149/1.1429224
Abstract
Mesoporous materials based on an aluminum-phosphorous-oxygen framework containing manganese and vanadium have been prepared with a pore spacing of roughly 4 nm. The mesoporous nature of the matrices was observed to degrade with increasing content of manganese or vanadium. The electrochemical performance of these matrices as lithium intercalation cathode materials was evaluated. Although their specific capacity is less than that of the corresponding metal oxides, these materials showed very good reversibility and rate capacity. © 2001 The Electrochemical Society. All rights reserved.Keywords
This publication has 21 references indexed in Scilit:
- Vanadium Oxide Nanotubes. A New Nanostructured Redox‐Active Material for the Electrochemical Insertion of LithiumJournal of the Electrochemical Society, 1999
- A 400 mAh/g Aerogel‐like V 2 O 5 Cathode for Rechargeable Lithium BatteriesJournal of the Electrochemical Society, 1998
- High Surface Area V 2 O 5 Aerogel Intercalation ElectrodesJournal of the Electrochemical Society, 1996
- Synthesis and Electrochemical Studies of Spinel Phase LiMn2 O 4 Cathode Materials Prepared by the Pechini ProcessJournal of the Electrochemical Society, 1996
- A 4 V Lithium Manganese Oxide Cathode for Rocking‐Chair Lithium‐Ion CellsJournal of the Electrochemical Society, 1994
- Study of amorphous and crystalline Li1+xV3O8 by FTIR, XAS and electrochemical techniquesSolid State Ionics, 1992
- Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanismNature, 1992
- The use of acetates as precursors for the low-temperature synthesis of LiMn2O4 and LiCoO2 intercalation compoundsJournal of Solid State Chemistry, 1991
- Birnessite manganese dioxide synthesized via a sol—gel process: a new rechargeable cathodic material for lithium batteriesElectrochimica Acta, 1991
- Li / Li1 + x V 3 O 8 Secondary Batteries: Synthesis and Characterization of an Amorphous Form of the CathodeJournal of the Electrochemical Society, 1990