Synthesis of (6R)- and (6S)-d-Glucose-6-2H through Stereospecific Photo-bromination of 1,6-Anhydro-β-d-glucopyranose Derivative

Abstract
A photo-bromination of l,6-anhydro-2,3,4-tri-O-benzoyl-β-d-glucopyranose and its [6,6-2H2]-derivative gave the corresponding (6S)-6-bromo compounds stereospecifically. They were transformed into (6S)-d-glucose-6-2H and (6R)-d-glucose-6-2H respectively.

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