Synthesis and crystal structure of tris-(2-picoline)copper(I) perchlorate (C6H7N)3CuClO4; a trigonal copper(I) ion

Abstract
Ionic copper(I) perchlorates, trico-ordinated by heterocyclic amines, have been prepared, characterized, and found to have trigonal hybridization about Cu; unusually high magnetic moments and Cu–N stretching frequencies are associated with some of these complexes.

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